The series tells the story of a 19-year-old Peter Parker in his first year at Empire State University, and his alter-ego Spider-Man. As the story begins, Peter has already gained his powers, is single and a part-time photographer for the Daily Bugle. The show features most of Spider-Man's classic villains, including the Kingpin, the Green Goblin, the Lizard, the Scorpion, Doctor Octopus, Mysterio, the Rhino, the Shocker, The Vulture, and the Chameleon, as well as more recent villains such as Venom, Carnage, and the Hobgoblin. Over the course of the series the single Peter Parker contends with the romantic interests of Mary Jane Watson, Black Cat and her alter ego, Felicia Hardy.
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